Evaporative Cooling of Helium Nanodroplets with Angular Momentum Conservation

Evaporative cooling of helium nanodroplets with angular momentum conservation.

Evaporative cooling of helium nanodroplets is studied with a statistical rate model that includes, for the first time, angular momentum conservation. While the final temperature of the droplets is almost identical to that previously predicted and later observed, the distribution of total droplet energy and angular momentum states is vastly more excited than a canonical distribution at the same ...

Angular momentum conservation in dipolar energy transfer.

Conservation of angular momentum is a familiar tenet in science but has seldom been invoked to understand (or predict) chemical processes. We have developed a general formalism based on Wigner's original ideas concerning angular momentum conservation to interpret the photo-induced reactivity of two molecular donor-acceptor assemblies with physical properties synthetically tailored to facilitate...

On momentum conservation and thermionic emission cooling

Angular momentum conservation for uniformly expanding flows

Angular momentum has recently been defined as a surface integral involving an axial vector and a twist 1-form, which measures the twisting around of space-time due to a rotating mass. The axial vector is chosen to be a transverse, divergence-free, coordinate vector, which is compatible with any initial choice of axis and integral curves. Then a conservation equation expresses rate of change of ...

Microcanonical Thermodynamic Properties of Helium Nanodroplets

Abstract The density of states and other thermodynamic functions of helium nanodroplets are calculated for a microcanonical ensemble with both energy and total angular momentum treated as conserved quantum numbers. These functions allow angular momentum conserving evaporative cooling simulations. As part of this project, a recursion relationship is derived for the reduction to irreducible repre...